Hi Pea, I have a list of poisonous plants given to me when I bought our pygmy goats - its a list for pygmy goats but I would imagine it would transfer to sheep pretty much. St John's Wort is listed as Medium in the Toxicity Level column and All Parts meaning roots leaves stems everything is poisonous - the name of the Toxin is Hypericin. To put the 'medium' in perspective, Hyacinth is the same level as is Hydrangea and Iris although the toxin in each of those has a different name, all deemed 'medium' though. A 'high' toxin is Laurel, Nightshade, Privet, Yew etc, the well known ones in other words.
We lost a north ronaldsay sheep earlier this year to Rhodedendron which we new was poisonous and had pulled one out but didn't see the little pathetic specimen that did the deed, so I am a bit paranoid myself. Thing is, our soay and moorit sheep had been in this part of the sheep field for ages and there had never been a problem, I did notice how much the ronaldsays browsed more than all our other sheep though, so perhaps its that some sheep may be attracted to browsing more than grazing and vice versa. Your present sheep may not have a problem and avoid it, whereas any new intake you may have may be attracted to it. I subsequently bought a book on poisonous plants which makes you want to burn your fields - everything looks poisonous!
Good luck.