We called into Bricomarché (a DIY store) and looked in the gardening section. Lo and behold was a product which appears the same as Rootout- crystals which are packed into holes drilled vertically or around the outside of the stump and called Décamp. Surprising this isn't sold in the garden centres though?
Results with copper nails appear to be dependent on the variety of tree, the number used and the position they are placed. I do know they used to use copper paint for anti-fowling on the underside of boats, so it is toxic (and now banned.)
Covering them up makes sense, but sometimes they sprout from roots well away from the main trunk. So it would perhaps work for Elderberry, but not for wild Damson.