You will get scalded above 50C. A stored water temperature of 60C is the legal minimum to avoid Legonella and 65C is considered the optimum. To resolve the scalding issue, which is a legal requirement on Public buildings and rental property, thermostatic mixing valves should be fitted at all the hot water outlets. These mix hot and an amount of cold to achieve a maximum outlet temperature of 50C or less.
I was very surprised when I was told (at Plumbing College) the difference between a cold shower and a hot one was just 5 degrees. 37C for cold and 42C for hot. Thermostatic showers are set to 42C maximum and have an override button which has to be activated to get past that.