To identify it accurately, you need to grow on a little piece, so you can see its eventual height and flowers.
But, if you let willowherb set seed it will quickly colonise any bare earth anywhere the seeds can reach on the wind. I don't know how long its seeds are viable in the ground. It's easy to pull out as its roots are not deep, and don't run like couch.
It's easy to shade it out, or pull it, or cut it, or graze it without resorting to weedkillers. It's a 'first coloniser', and once other plants start to grow around it, it moves on to fresh ground.
The chemical you mean Sally is aminopyralid - hateful stuff and ubiquitous.