I wondered if that was what you meant by poisonous.
In fact most food designed for non ruminants will kill a ruminant if they eat too much of it. I lost a lovely Suffolk ram because he got into the henhouse and helped himself to half a bag of wheat. The food itself is not exactly poisonous, but like you say, causes the wrong fermentation in the rumen and the animal dies of enterotoxaemia. It is the quantity of the unaccustomed food that kills, as the bacteria in the rumen cannot instantly adapt to it and digest it before it has fermented.