Goats milk may separate a little on defrosting... depending on how long it has been frozen.... but it should completley re mix on being whisked.
There should be NO change in taste what so ever.
I have frozen milk for over a year and it was perfectly good for human drinking... needed whisking.
Does your milk have a goaty taint... thus can affect the tawing... your goats are possibly short of cobalt in their diet, this causes the goaty flavour & can change the character of the milk.
There are many goats in UK that are short of cobalt... it is dietary. 2 ways to cure, 1 - is a cobalt bolus into the rumen, goes down the throat. 2 - change the diet for a cattle dairy nut. All cattle food is higher in minerals than goat/sheep/general purpose mix. The area they are grazing may also contibute... hence why I always recommend a soil analysis being done, it is very cheap usually but gives peace of mind. Don't forget your hay , if bought locally, could be short of the same minerals.