I think you're supposed to do it at day old (someone correct me if I'm wrong). Try YouTube vids.
I do know someone who has vent sexed older geese. We may have to do it with ours shortly as I suspect that one of my ladies has turned out male. The other male we have is fairly obvious and he has a mark on him so I can distinguish him from the others, but with this other 'possibility' I am having to go on behaviour rather than size etc.
Can I recommend Azzdodd that you get some leg rings if you are going to handle them anyway (save doing it later on), it will be helpful to you next year if you are breeding - just got some myself from Regency Poultry via ebay - make sure you get the big size.
Let us know how you get on.