A friend of mine , well an acquaintance more like, has such a green house and it appears to be all worked wood joints , it's made out of western red cedar , it must be a good 25 yrs or more old. western red cedar doe not need a preservative .
Once you makke a decent jig or three cutting repeatable joints is a breeze with a decent 1/2" router & cut to length planed timbers.
The rebated window panes are made from cut to size perspex that has been set in place & sealed with a long term flexible mastic which means that over the years they have gone opaque but still let the light in and it last much longer than poly greenhouse sheeting's. The whole thing is set on cut to size outdoor concrete blocks that were set up on a concrete foundation ,all are properly pointed as well. If I remember rightly there are also three windows that can be opened and kept open on a lockable window stay . Though now I have automatic venting stays on my big green house if I were to make another green house of any shape I'd be using the auto venting stuff .
I gather that a welded metal jig was used so that a petrol disc cutter could quickly cut things to the right angle .. The rules of trig & geometry needed for this exercise say that the angles will be opposite and equal & congruent
) so it's just a case of turning one block over to get the correct angles and infilling the difference with block work cut at 90 degrees . The bottom row of frames were set on a couple of beads of long life flexible mastic and also coach screwed and wall plugged to the block base.